1,4-Bis(pyridin-3-ylmethoxy)benzene
نویسندگان
چکیده
The asymmetric unit of the centrosymmetric title compound, C(18)H(16)N(2)O(2), contains one half-mol-ecule. The central benzene ring forms a dihedral angle of 66.8 (1)° with two outer aromatic rings. In the crystal structure, weak inter-molecular C-H⋯N hydrogen bonds link mol-ecules into sheets parallel to (104).
منابع مشابه
catena-Poly[[dichloridozinc(II)]-μ-1,4-bis(pyridin-2-ylmethoxy)benzene-κ2 N:N′]
In the title compound, [ZnCl(2)(C(18)H(16)N(2)O(2))](n), the Zn(II) ion is tetra-hedrally coordinated by two Cl atoms and by two N atoms from different 1,4-bis-(pyridin-2-ylmeth-oxy)benzene ligands. The ligand shows a non-planar configuration, in which the dihedral angles between the two terminal pyridine rings and the linking benzene ring are 7.86 (12) and 70.74 (11)°. The flexible ligand coor...
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Coordination polymers and a macrocycle formed from the reactions between flexible bis(2-pyridyl) ligands and AgCF(3)SO(3) are reported. The type of structure formed depends on the choice of ligand and the stoichiometry of the reaction. When 1 equiv of 1,4-bis(pyridin-2-ylmethoxy)benzene (L2), 4,4'-bis(pyridin-2-ylmethoxy)biphenyl (L4), or bis((4-pyridin-2-ylmethoxy)phenyl)methane (L5) is used, ...
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The synthesis and characterization of dinuclear ruthenium polypyridyl complexes based on the bridging ligands 1,3-bis-(5’-(pyridin-2’’-yl)-1’H-1’,2’,4’-triaz-3’-yl)-benzene, 1,4-bis-(5’-(pyridin-2’’-yl)-1’H-1’,2’,4’-triaz-3’-yl)-benzene, 2,5-bis-(5’-(pyridin-2’’yl)-1’H-1’,2’,4’-triaz-3’-yl)-thiophene, 2,5-bis-(5’-(pyrazin-2’’-yl)-1’H-1’,2’,4’-triaz3’-yl)-thiophene, and of their mononuclear anal...
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In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Co(II) ion is located on an inversion center and is six-coordinated in an octa-hedral environment defined by four N atoms of the pyridine rings and two O atoms of the nitrate anions. The ligands link the Co(II) ions into a linear chain running along [201]. One O atom of the nitrate ligand is disordered over two positions with ...
متن کاملcatena-Poly[[bis(nitrato-κO)cadmium]bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the n...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009